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Polyurethanes are different from most plastic materials in
that they can be tailored to meet the requirements of varying
applications. Soft elastomers in flexible foams with low density
are used in cushions and bedding. Tougher elastomers with higher
densities are used for soles of shoes and boots. Rigid foams are
used in construction, automobiles, furniture, boating, and many
other applications.

History
The commercial potential of polyurethane chemistry was
first recognized in the late 1930s. I.G. Farben
(Germany), ICI (U.K.), and du Pont (U.S.A.) developed a
variety of applications. ICI introduced rigid foams in
1957. Production line insulation for refrigerators was
introduced in 1963. In 1968 General Motors started making
polyurethane bumpers for the Pontiac G.T.O. The
combination of strength to support loads and thermal
insulation made rigid polyurethane foam an attractive
material for the cryogenic pipe supports required for
major LNG facilities constructed in the 1970s.
Pipe Support Design
The primary design parameter for the polyurethane
component of a pipe support is density because this
determines the compressive strength. As shown in Figure
1, on a log-log scale the relation between compressive
strength and density is linear. Tensile strength also has
a linear log-log relation to density. Because the loads
on supports for larger diameter pipes are larger than
those on polyurethane components in many other industrial
applications, we require higher density materials. For
components used in pipe supports with densities from 10
to 40 pounds/cubic foot (160 to 640 kg/cubic meter),
particularly those produced in molds, the compressive
strength is essentially the same in all directions.
Thermal conductivity is another design parameter of
concern for the pipe support designer. For rigid foam polyurethanes, thermal conductivity increases with
density. Fortunately, the 10 to 40 pound-density
materials are less sensitive to the choice of blowing
agent and aging, two concerns for industries which use
low density foams to achieve very low thermal
conductivity.

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